Before you lose interests to read on (because you don’t know or care about polymer or diffusion or surface or all of them), please picture yourself walking around in your own apartment. Let me ask you where you walk faster, on the kitchen floor tile, or the bedroom carpet? You might wonder what a trivial question I walk at more or less the same speed! OK. Now you leave your apartment and walk to your lab. I will time you. First, you take the sidewalk, five minutes. Next, evil and omnipotent as I am, I will put a hill on your way. Now you have to climb over it to get to the lab. I won’t be too surprised if it takes you longer.
You might take these scenarios for granted. But can you imagine if you were the size of an ant, the bedroom carpet became endless hills that had to be climbed? Or if you were as tall as maybe Mt. Everest, you wouldn’t even notice there was a hill in your way as you pass it. So, the relative size matters! For polymers moving on a surface, my labmate Janet Wong recently shows us that relative length scale matters too. Long and short polymer chains feel the different roughness for the same surface. One thing I hope to do is to be more quantitative on this.
The story can be more complex. To give you some flavor, when put in a solvent, do polymer chains swim near the surface but not touch it, or they crawl on a surface as if many feet are touching the ground? Is the ground sticky? What do they look like? A messy coil, a stretched long chain, or a rigid rod…
[offscreen]: She is still at the early stage of teaching her polymer pets to behave. It will probably take just a few more years before she really starts to get down to asking these questions. But she is trying.